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Water

H2O inorganic

Properties

StateLiquid at room temperature
ColorColorless
SolubilityMiscible with most polar solvents (methanol, ethanol, acetone, DMSO); immiscible with most nonpolar solvents
Melting Point0 °C (273.15 K) at 1 atm
Boiling Point100 °C (373.15 K) at 1 atm

About Water

Water, H2O, is the molecule that anchors most of the constants and reference points you encounter in a chemistry lab. Two O-H bonds at a 104.5 degree angle, a sizeable dipole moment, and an extensive hydrogen-bond network give water its unusually high boiling point (100 °C at 1 atm), high specific heat capacity (4.184 J/g/K), and a density anomaly that makes ice float. Pure water at 25 °C autoionizes weakly to give [H+] = [OH-] = 1.0 × 10^-7 M, which is what fixes neutral pH at 7.00 — that number is not arbitrary, it falls out of Kw = 1.0 × 10^-14 at 25 °C and shifts with temperature (Kw at 100 °C is closer to 5.5 × 10^-13, so neutral pH is roughly 6.13 in boiling water). Water is the solvent in which most aqueous acid-base, redox, and complexation chemistry is defined; the calorie was originally tied to it; the kilogram was tied to it through 1901; the Celsius scale brackets its triple-point and atmospheric boiling point. As a chemical reactant water shows up in hydrolysis, hydration, condensation, and acid-base neutralization, and as a solvent it dissolves more ionic and polar substances than any other common liquid.

Where you'll encounter it

If you've ever calibrated a pH meter with the standard 4, 7, and 10 buffers, run a titration to a phenolphthalein endpoint, or watched ice cubes drop into a glass and wondered why they float, you've used water as both reagent and reference. In a Type I purification system feeding ICP-MS or HPLC, water is polished to 18.2 megohm-cm resistivity at 25 °C, less than 5 ppb total organic carbon, and run through a 0.22 micron final filter — those specifications fall directly out of how much instrument noise residual ions and TOC will inject. Calorimetry students spend their first lab measuring the specific heat of an unknown metal by dropping it into a known mass of water and applying q = mc(deltaT), with water's 4.184 J/g/K specific heat as the calibration anchor. Drinking-water utilities run jar tests on raw source water with alum or ferric chloride to optimize coagulant dose before the water hits the rapid mix at the plant inlet.

Common Uses

  • Solvent of record for aqueous acid-base, redox, and coordination chemistry
  • Coolant and heat-transfer fluid in nuclear, automotive, and industrial process equipment
  • Reactant in hydrolysis, hydration, and acid-base neutralization reactions across organic and inorganic synthesis
  • Reference substance for the kilogram, calorie, Celsius scale, and specific gravity definitions
  • Calibration medium for densitometers, refractometers, and calorimeters in analytical labs
  • Mobile-phase component for reverse-phase HPLC and ion chromatography separations
  • Working fluid in steam turbines, hydraulic systems, and pressure vessels for power generation

Safety Information

Pure water is non-toxic, non-flammable, and the substance against which most workplace exposure limits are normalized. Drinking water at typical municipal supply rates carries no acute toxicity, but rapid intake of several liters within a few hours can cause hyponatremia (water intoxication) by diluting serum sodium below 135 mEq/L, with seizures and cerebral edema as terminal symptoms. There is no OSHA PEL or GHS classification for water itself. Note the practical hazards of state changes: steam at 100 °C delivers the latent heat of vaporization (2257 J/g) to skin on contact and causes deeper burns than equivalent-temperature liquid water, and contact between liquid water and molten metals or strong dehydrating agents like H2SO4 can be violently exothermic. Always add concentrated acid to water, not the reverse.

This safety summary is for educational reference only and may not be complete. It is not a substitute for Safety Data Sheets (SDS), medical advice, or professional chemical safety guidance. Always consult appropriate SDS and qualified professionals before handling chemicals.

Constituent Elements

Frequently Asked Questions

What is the molar mass of water?
Water (H2O) has a molar mass of 18.015 g/mol: 2 H (2 x 1.008 = 2.016) plus 1 O (15.999). At standard temperature, 1 mole of liquid water occupies 18.015 / 0.997 = 18.07 mL, which is the basis for the back-of-envelope rule that '1 mol of water is roughly one tablespoon.' That number gets used constantly in stoichiometry problems involving hydrates and condensation reactions.
Why is water called the universal solvent?
Water dissolves more substances than any other common solvent because its molecular dipole and hydrogen-bond donor/acceptor capability stabilize a wide variety of ionic and polar solutes. The high dielectric constant of water (about 80 at 25 °C) screens the electrostatic attraction between dissolved cations and anions, allowing salts to dissociate. Polar molecules like sugars and alcohols are stabilized through hydrogen bonding to the water network. The 'universal' label is informal — water is poor at dissolving nonpolar hydrocarbons and many organics.
What is the pH of pure water?
Pure water at 25 °C has pH 7.00, which is neutral by definition because [H+] equals [OH-] at exactly 1.0 × 10^-7 M and Kw is 1.0 × 10^-14. That number shifts with temperature: at 0 °C neutral pH is about 7.47, and at 100 °C it drops to about 6.13. The water is still chemically neutral at every temperature, but the numerical value of neutral pH tracks the temperature dependence of Kw.